1.Consider the molecule azulene and
a) set the secular determinant for azulene within the huckel approximation and using the out of plane C2p orbitals as basis set.
b) Estimate pi electron binding energy within the Huckel approximation
c) Approximate the delocalization energy

Answers

Answer 1
Mark Brainliest please

Answer :

The Hückel approximation is used to determine the energies and shapes of the π
π
molecular orbitals in conjugated systems. Within the Hückel approximation, the covalent bonding in these hydrocarbones can be separated into two independent "frameworks": the σ
σ
-bonding framework and the the σ
σ
-bonding framework. The wavefunctions used to describe the bonding orbitals in each framework results from different combinations of atomic orbitals. The method limits itself to addressing conjugated hydrocarbons and specifically only π
π
electron molecular orbitals are included because these determine the general properties of these molecules; the sigma electrons are ignored. This is referred to as sigma-pi separability and is justified by the orthogonality of σ
σ
and π
π
orbitals in planar molecules. For this reason, the Hückel method is limited to planar systems. Hückel approximation assumes that the electrons in the π
π
bonds “feel” an electrostatic potential due to the entire σ
σ
-bonding framework in the molecule (i.e. it focuses only on the formation of π
π
bonds, given that the σ
σ
bonding framework has already been formed).


Related Questions

Can anyone help me with this question?

Can anyone help me with this question?

Answers

sure i can help

so u have to ask someone else

What is the purpose of the arrow in a chemical equation?

Answers

The arrow in a chemical equation represents the direction of the reaction. It indicates the conversion of reactants into products. The arrow points from the reactant side to the product side, symbolizing the flow of the reaction.

The purpose of the arrow is to visually represent the chemical transformation occurring in the reaction. It shows the relationship between the reactants and products and the direction in which the reaction proceeds. The arrow implies that the reactant molecules are being rearranged and transformed into new substances with different properties.

Chemical equations are used to describe the stoichiometry and balance of reactions. The arrow helps convey this information by illustrating the overall process taking place. It serves as a crucial element in understanding the reaction's composition, reaction conditions, and the substances involved.

Furthermore, the arrow also implies that the reaction can occur in both directions. In reversible reactions, the arrow can be represented as a double-headed arrow, indicating that the reaction can proceed in either direction depending on the conditions.

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Some students use an apple to represent the Earth. What is the best reason to use an apple for this comparison?

a. The skin of an apple is very thin, and the crust of the Earth very thin.

b. The flesh of an apple is made of the same material all the way through, and the interior of the Earth is the same all the way through.

c. The seeds of the apple are very light in comparison to the rest of the apple, and the core of the Earth is also made of very light matter.

d. The stem of the apple comes from the core and the North Pole comes from the Earth’s core.

Answers

C.The seeds of the apple are very light in comparison to the rest of the apple, and the core of the earth is also made of very light matter.

Why was meteorology such a late developer compared to other branches of science?

Answers

Answer:

Because of the difficulties of measuring the atmosphere's properties above the earth's reachable surface

Explanation:

Hello,

In this case, meteorology is the branch of science studying the atmosphere in its weather processes and forecasting and it had a late development because of the difficulties of measuring the atmosphere's properties above the earth's reachable surface. We cannot forget that even nowadays, it is very difficult to predict upcoming weathers with the 100 % assurance and with many days in advance.

Best regards.

Meteorology is developed lately as compared to other branches of science due to far away from the reach of humans.

Meteorology is a late developer compared to other branches of science because the measuring the climatic conditions in the atmosphere is difficult and even impossible without the presence of advance technologies.

To find out the weather as well as climatic conditions can't be measured due to it is not reachable to the human like other materials present on the earth surface so we can conclude that meteorology is developed lately as compared to other branches of science due to far away from the reach of humans.

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In which orbitals would the valence electrons for selenium (Se) be placed?

Answers

Answer:

Valence electrons of selenium will be placed in s and p-orbitals.

Explanation:

Hope this helps.

which of the following best describes colloids?

A. clear, flawless substances
B. clear, pure substances
C. dark, black substances
D. sticky, creamy substance

nonsense=report T_T​

Answers

answer B, because clear ,pure substances makes more sense then others, i searched it all up and came up b, please give brainliest!! good luck

Answer: it's definitely b since its the one that makes the most sense plus i look it it up and im certain it is B

Prepare one solution that has 0.12 M of FeCl3 and 0.40 M of HCl with the reagents 3 M HCl and Solid FeCL3 * 6H20. Provide the calculations and protocol to make the solution in a lab.

Answers

To prepare a 0.12 M solution of FeCl₃, the amount of solid FeCl₃ to be dissolved in a given volume of solvent will be 9.72 grams.

Given,

Molarity of FeCl₃ (M)= 0.12 M

The molecular weight (m) of FeCl₃ is  = 162 gm

The volume of the solution (V) to be prepared is =500 ml

The amount of FeCl₃ to be dissolved to make a 0.12 M solution is= x

So,

MV= x ÷ m × 1000

0.12× 500 = x ÷ 162 × 1000

x = 60 × 162 ÷ 1000

x= 9.72 gm

So 9.72 grams of FeCl₃ is dissolved to make 500 ml of 0.12 M solution.

For preparing 0.4 M HCl from 4M HCL:

If we need to make 500 ml of solution with 0.4M of HCL, then we use the formula:

M₁V₁= M₂V₂

0.4 × 500= 4 × x

x= 50 ml

So 50 ml of 4M HCL is taken to make 0.4 M HCL.

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Explain the principles behind an acid-base titration. What is an indicator?

Answers

An acid–base titration is a method of quantitative analysis for determining the concentration of an acid or base by exactly neutralizing it with a standard solution of base or acid having known concentration. A pH indicator is used to monitor the progress of the acid–base reaction.

There is no change in the concentration of the reactants or the products.

When a reversible process reaches equilibrium,

The forward reaction rate is the same as the backward reaction rate.

The quantity of product being formed is therefore equal to the quantity of reactant being formed in a given amount of time.

Therefore, for a reversible reaction at equilibrium, both the reactant concentration and the product concentration are constant.

Indicators can be used to roughly determine the equivalence point of an acid-base titration as this colour shift only happens over a narrow pH range.

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The principle behind the acid-base titration is that at the equivalence point , is where the no. of moles of the OH⁻ and H⁺ is equals. . indicator is the dye that color depends on the acidity or the basicity of solution.

The principles in which the acid - base titration is based on is that at the equivalence point the number of the moles of the OH⁻  ions and the number of moles of the  H⁺ both are equals. in the neutralization reactions the acid and the base will react and form the salt and the water.

An indicator is the dye or the chemical substances the will indicates the nature of the acidic and the basic solution.

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Name the organic compound of ch2=chch2ch3

Answers

I don’t know what exactly is but see at the picture.
Name the organic compound of ch2=chch2ch3

How much heat must be added to a 34.2 g sample of aluminum in order to raise the temperature of the aluminum 34 oC? (The specific heat of Aluminum is 0.9 J/g oC)

Answers

The amount of heat required to raise the temperature of the 34.2 g sample of aluminum by 34 oC is 1043.52 J.

What is Temperature?

Temperature is a measure of the average kinetic energy of the particles in a substance. It is a physical property that determines the direction of heat flow between two objects or systems in contact with each other. Temperature is measured in degrees Celsius (°C) or Fahrenheit (°F), or in kelvin (K) in the International System of Units (SI).

The amount of heat (q) required to raise the temperature of a substance can be calculated using the formula:

q = m x c x ΔT

Where:

m = mass of the substance (in grams)

c = specific heat of the substance (in J/g oC)

ΔT = change in temperature (in oC)

Plugging in the values given:

m = 34.2 g

c = 0.9 J/g oC

ΔT = 34 oC

q = (34.2 g) x (0.9 J/g oC) x (34 oC)

q = 1043.52 J

Therefore, the amount of heat required to raise the temperature of the 34.2 g sample of aluminum by 34 oC is 1043.52 J.

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what tools are used specifically for earth science

Answers

Geologic Tools. Geologists use a lot of tools to aid their studies. Some of the most common tools used are compasses, rock hammers, hand lenses, and field books.

hope this helped <3

dropping an Alka-Seltzer tablet into a glass of water _________________________________________ b. bleaching a stain _________________________________________ c. burning a match _________________________________________ d. rusting of an iron nail

Answers

Answer:

Hi there!

When dropping Alka-Seltzer into a glass of water, bubbles immediately appear and the solid substance “disappears”, dissolves, into the water. This forms a new compound, a liquid, which means a reaction took place.

What is the heat of a reaction, in kJ/mol, with a total reaction mixture mass of 62.6 g if the reaction of 0.15 mol of reactant A causes a temperature increase of 4.6 oC in a calorimeter

Answers

Answer:

\(-8.032\ \text{kJ/mol}\)

Explanation:

m = Mass of mixture = 62.6 g

n = Number of mole of reactant = 0.15 mol

\(\Delta T\) = Change in temperature = \(4.6^{\circ}\text{C}\)

c = Specific heat of mixture = \(4.184\ \text{J/g}^{\circ}\text{C}\) (assumed to be the same as water)

Heat generated

\(Q=mc\Delta T\\\Rightarrow Q=62.6\times 4.184\times 4.6\\\Rightarrow Q=1204.82\ \text{J}=1.20482\ \text{kJ}\)

Heat of reaction is given by

\(\Delta H=-\dfrac{Q}{n}\\\Rightarrow \Delta H=-\dfrac{1.20482}{0.15}\\\Rightarrow \Delta H=-8.032\ \text{kJ/mol}\)

The heat of the reaction is \(-8.032\ \text{kJ/mol}\)

A 62.6 g-reaction mixture that contains 0.15 moles of reactant A and causes a temperature increase of 4.6 °C in a calorimeter, has a heat of reaction of -8.0 kJ/mol.

We have a reaction mixture in a calorimeter that causes a temperature increase of 4.6 °C (ΔT). We can calculate the heat absorbed by the solution (Qs) using the following expression.

\(Qs = c \times m \times \Delta T = \frac{4.184J}{g.\° C} \times 62.6 g \times 4.6 \° C \times \frac{1kJ}{1000J} = 1.2 kJ\)

where,

c: specific heat capacity of the solution (we will assume it is the same as water)m: mass of the solution

According to the law of conservation of energy, the sum of the heat absorbed by the solution and the heat released by the reaction (Qr) is zero.

\(Qs + Qr = 0\\\\Qr = -Qs = -1.2 kJ\)

1.2 kJ are released by the reaction of 0.15 moles of reactant A. The heat of the reaction, in kJ/mol, is:

\(\frac{-1.2kJ}{0.15mol} = -8.0 kJ/mol\)

A 62.6 g-reaction mixture that contains 0.15 moles of reactant A and causes a temperature increase of 4.6 °C in a calorimeter, has a heat of reaction of -8.0 kJ/mol.

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Which chemical equation is balanced?
O A. Fe + O₂ → Fe2O3
O B. 2 Fe + 0₂ - > Fe₂O3
O C. 2 Fe + 3 0₂ Fe2O3
D. 4 Fe + 3 0₂ 2 Fe2O3

Answers

Answer:

F

Explanation:

The balanced chemical equation is option D:

4 Fe + 3 O₂ → 2 Fe₂O₃

This is a balanced equation because:

- There are four iron (Fe) atoms on both the reactant and product sides.

- There are three oxygen (O₂) molecules on both the reactant and product sides.

- The coefficients are the smallest possible integers that make the equation balanced.

How much does 0.25 mol C weigh?
HELP

Answers

Answer: I am pretty sure it would be 3.002675

Explanation: 1 moles carbon is 12.0107 grams so divide that by 4 (0.25) and you get 3.002675

Avagadro’s number:

A: Is constant irrespective of mass of the gases

B: Varies according to the mass of the gases

C: Varies according to the pressure on the gases

D: All of the Above

Answers

Answer:

A: Is constant irrespective of mass of the gases

Explanation:

Avagadro's number, denoted by nA, is a number that represents the units in one mole of any substance. The number is 6.02214076 × 10²³ and the units can be atoms, molecules, ions, formula units etc.

That is;

1 mole of a substance = 6.022 × 10²³atoms, molecules, ions, electrons etc.

It is important to note that the Avagyadro's number is constant irrespective of mass of the gases that are involved.

NOMBRA LAS SIGUIENTES ESTRUCTURAS

NOMBRA LAS SIGUIENTES ESTRUCTURAS

Answers

La nomenclatura IUPAC tiende a eliminar las ambigüedades asociadas con la existencia de diferentes nombres para la misma estructura.

¿Cuál es el nombre de la estructura?

IUPAC, que implica que la Unión Internacional de Química Pura y Aplicada ha establecido reglas grupales para la denominación de compuestos. Este sistema de IUPAC tiende a eliminar las ambigüedades asociadas con la existencia de diferentes nombres para una misma estructura.

Los siguientes son los nombres de los compuestos;

a) 3,7 -dimetildecano

b) 2,4- dietil ciclopentano

c) 2-etil-3-propil-6-metilheptano

d) 2-etil propano

e) 2,4-dietil-5-metil ciclohexano

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3. What are the three states of matter? Name at least three phase changes.

Answers

Answer:

The 3 states of matter are Solid, Liquid, and Gas.

Explanation:

Some phases changes include

condensationvaporizationfreezingmeltingdeposition sublimation

Classify each of the following as elements (E), compounds (C) or Mixtures (M). Write the letter X if it is none of these. ______Diamond (C) ______Sugar (C6H12O6) _______Milk ____Iron (Fe) _____Air ______Sulfuric Acid (H2SO4) _______Gasoline (hydrocarbons) _____Electricity ______Krypton (K) ___Bismuth (Bi) ___Uranium (U) _______Kool-Aid ___Water (H2O) _____Alcohol (CH3OH) ______Pail of Garbage ___Ammonia (NH3) ___Salt (NaCl) ______Energy ______Gold (Au) _______Wood _______Bronze _______Ink ______Pizza ______Dry Ice (CO2) ______Baking Soda(sodium bicarbonate)

Answers

Answer:

Diamond - E

Sugar- C

Milk - M

Iron- E

Air- M

Sulfuric Acid- C

Gasoline - M

Electricity- X

Krypton- E

Bismuth - E

Uranium - E

Kool-Aid -M

Water - C

Alcohol - C

Pail of Garbage - M

Ammonia - C

Salt - C

Energy - X

Gold - E

Wood - M

Bronze - M

Ink - M

Pizza - M

Dry Ice - C

Baking Soda - C

Explanation:

An element is the smallest part of a substance that is capable of independent existence. An element cannot be broken down into any other substance. Krypton, Bismuth etc are all elements.

A compound is a combination of two or more elements which are chemically combined together e.g NH3, CO2 etc.

A mixture is any combination of substances that are not chemically combined together. E.g Pizza, milk etc

When two species A and B form an electron-pair bond and A does not provide its electrons for bonding, the bond present between A and B must be

Answers

Answer:

Ionic

Explanation:

If A does not have electron to bond, it just receives one electron from B.

It can´t be covalent because A don´t have any electrons to bond with B.

7. The lowest whole-number ratio of the elements in a compound is called the
O empirical formula
O binary formula
O molecular formula
O representative formula

Answers

Answer: empirical formula is the answer. ur welcome.

Explanation:

Answer:

empirical formula

Explanation:

just took test

why is platinum metal preferred to other metals for the flame test​

Answers

Answer:

Platinum is especially good for this because it is unreactive, and does not produce a color in the flame which will mask the presence of other metals.

Hope this answer is right!

Answer:

Hey mate, here is your answer

1. Platinum doesn't impart any color to the flame.

2. It is not oxidised under the high temperature of the flame from a bunsen burner.

3. It is almost chemically inert. Even at high temperatures, it remains unattacked by free radicals / acid radicals.

Therefore, platinum wire is crucial for a flame test. Also, a platinum wire should be thoroughly cleaned before using it for a new flame test.

A platinum wire is cleaned by dipping it into concentrated HNO3 and then placing it in the non luminous part of the bunsen flame. Otherwise, the perviously tested radicals will impart color to the flame, which may cause confusion.

Explanation:

Hope it helps you

The meaning of the word symptom:​

Answers

The word "symptom" refers to a specific manifestation or indication of a condition, disease, or disorder that is experienced or observed by an individual.

Symptoms are subjective or objective changes in the body's normal functioning that may be recognized as abnormal, uncomfortable, or problematic. Symptoms can manifest in various ways depending on the nature of the underlying condition. They can be physical, such as pain, rash, cough, fever, or fatigue, indicating an illness or injury affecting the body. Symptoms can also be psychological, such as anxiety, depression, or confusion, reflecting disturbances in mental health.

Symptoms serve as important clues for medical professionals to identify and diagnose diseases or disorders. They provide valuable information about the nature, severity, and progression of an illness, helping healthcare providers formulate appropriate treatment plans. Additionally, symptoms may also be important for individuals to self-assess their own health status and seek appropriate medical attention.

It is essential to note that symptoms alone may not provide a definitive diagnosis, as they can overlap across different conditions. Further evaluation, including medical tests and examinations, is often necessary to confirm a diagnosis and determine the appropriate course of action.

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Onisha wants to sort 20 objects into
groups by their color. She wants to record
what object was in each group. Which
would be the best way to record her
sorting?
A Draw each of the objects she sorted
and staple each drawing into a group.
B Make a chart and list the objects into
groups the way she sorted them.
Make a bar graph that shows how
many objects of each color there are.
D List all the objects and put a
checkmark by all the blue objects.p

Answers

Answer: B

Step-by-Step Explanation:

Which statement about subtatomic particles are true

Answers

The statement about sub-atomic particles that is true is:

Electrons are the subatomic particles with the smallest mass; option B

What are sub-atomic particles?

Sub-atomic particles refer to the smaller particles that are the constituents of atoms of elements.

There are three sub-atomic particles within a given atom,

The three sub-atomic particles are given below:

electrons -electrons are the negatively charged particles found outside the nucleus of an atom in electron shells or orbitals around the atom.protons - these are positively charged particles found inside the nucleus of an atom. The number of protons in an atom gives the atomic number of that atom.neutrons - these are neutral atoms found in the nucleus of atoms. The sum of the neutrons and protons in the nucleus of an atom gives the mass number of an atom. This is because the mass of an at is centered inside the nucleus since the proton and neutron have equal mass but the electron has negligible mass.

Considering the given statements about the sub-atomic particles, the only true statement is that which describes the mass of the electron as being the smallest of the three sub-atomic particles.

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Complete question:

Which statement about subatomic particles is true?

Protons are the only subatomic particles to have a charge.

Electrons are the subatomic particles with the smallest mass.

Neutrons orbit the nucleus of the atom.

Subatomic particles all have the same mass

scientist wants to use a model to help present the results of his detailed scientific investigation.

Why would a model be useful?
because the model makes the concepts easier to understand
because the model is easy to put together and to use
because the model prevents other scientists from asking questions
because the model requires the audience to pay full attention to it

Answers

Answer: A model would be useful because the model makes the concepts easier to understand.

Explanation:

Models are helpful tools in science education that can be used to enhance explanations, spark discussion, make predictions, provide visual representations of abstract concepts, and create mental models.

Please help. Thank you so much

Please help. Thank you so much

Answers

Enthalpy change (H) and entropy change (S) are 11.7 103 Jmol-1 and 105 Jmol-1K-1, respectively, for a reaction at 25 °C.

What is the change in the free basic energy at 25 °C?

The absolute entropies of a reactants and their products are S°(N2H4) (= half of this period J/(mol•K), S°(N2) = 191.6 J/(mol•K), or S°(H2) = 130.7 J/(mol•K) at 25°C, where the standard enthalpy change (H°) is 50.6 kJ/mol.

What is the calomel electrode's reduction potential at 25 C?

E0 is known as 0.268 V at standard potential at 25°C, despite a slight variation in the computed value above. Similar to a silver-silver chloride electrode, the electrode potential is dependent on the chloride ion concentration.

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Larissa needs to make 500ml of 2.00 M NaCl. The molecular weight of NaCl is 58.44. How does she make 500ml of 2.00 M NaCl? Question 3 options: A) Measure 29.22g NaCl and dissolve it into 500ml water. B) Measure 29.22g NaCl, dissolve it into 400ml water, and then top off to 500ml in a volumetric flask. C) Measure 58.44g NaCl and dissolve it into 500ml of water. D) Measure 58.44g NaCl, dissolve it into 400ml water, and then top off to 500ml in a volumetric flask.

Answers

Answer:

D) Measure 58.44g NaCl, dissolve it into 400ml water, and then top off to 500ml in a volumetric flask.

Explanation:

Step 1: Given data

Molarity (M): 2.00 M

Volume (V): 500 mL = 0.500 L

Molar mass of NaCl: 58.44 g/mol

Step 2: Calculate the required moles of NaCl

We will use the following expression.

n = M × V

n = 2.00 mol/L × 0.500 L

n = 1.00 mol

Step 3: Calculate the mass corresponding to 1.00 moles of NaCl

1.00 mol × 58.44 g/mol = 58.44 g

Step 4: Describe the procedure to prepare the solution

Measure 58.44g NaCl, dissolve it into 400ml water, and then top off to 500ml in a volumetric flask.

Answer:

D) Measure 58.44g NaCl, dissolve it into 400ml water, and then top off to 500ml in a volumetric flask.

Explanation:

I got it right in class!

Hope  this helps!! :))

What is the molarity of a HCl solution that
contains 7.68 g of HCl in 253 mL of solution?
Answer in units of M. Answer in units of
M.

Answers

Answer:

The first step is to convert the given mass of HCl to moles:

moles of HCl = mass of HCl / molar mass of HCl

moles of HCl = 7.68 g / 36.46 g/mol

moles of HCl = 0.2103 mol

Next, we need to convert the given volume of solution to liters:

volume of solution = 253 mL = 0.253 L

Now we can calculate the molarity of the solution:

molarity = moles of solute / volume of solution

molarity = 0.2103 mol / 0.253 L

molarity = 0.831 M

Therefore, the molarity of the HCl solution is 0.831 M.

Explanation:

1. Write the molecular balanced equation for the dissolution of copper. 2. Write the complete ionic balanced equation for the dissolution of copper. 3. Write the net ionic balanced equation for the dissolution of copper. 4. What type of reaction is this

Answers

Answer:

Cu + HNO3 -----> Cu (NO3) 2 + NO2 + H2O

Explanation:

This equation is the equation for dissolving copper in nitric acid, this reaction is a REDOX reaction, that is, an oxide-reduction reaction.

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