Answer: c6h12o6+6o2→6co2+6h2o= C6H12O6 + 6O2 -> 6CO2 + 6H2O Yields 2755 kJ/mole of glucose. The reverse of this reaction – combing carbon dioxide and water to make sugar is known as photosynthesis. Photosynthesis is the process responsible for storing all the energy we extract from fossil fuels, crops, and all of our food. We will also see that it is part of a globally important cycle affected by our consumption of fossil fuels. Photosynthesis How is photosynthesis able to run the reaction above in the reverse direction? Somehow it must come up with 2755 kJ of energy to make each mole of glucose. Where does that energy come from? The short answer: photons of sunlight. The long answer: When the pigment chlorophyll inside the chloroplasts of a photosynthetic organism (phytoplankton, trees, other plants) absorbs sunlight, it becomes energetically ‘excited’ and grabs the hydrogen atoms away from a water molecule, leaving the oxygen atoms to escape as O2 gas. This is called ‘splitting water.’ The hydrogen atoms are then split into their component protons and electrons. The electrons are used to reduce carbon dioxide, in a series of many steps requiring more absorption of sunlight by chlorophyll, to glucose. When carbon dioxide receives those electrons, the extra negative charge attracts protons from elsewhere, creating hydrogen atoms attached to the carbon atom. This process is called reduction. When those reduced carbon dioxide molecules are combined together in a larger molecule, the result is glucose. This ‘combing together’ of small molecules requires an input of energy, which is provided by the ATP molecules made by the protons diffusing through the membrane of the chloroplast. The ATP molecule is simply a molecule that biology uses to store energy for later use. In this case, the mechanical energy created by the protons diffusing across the membrane turns a sort of molecular turbine that smashes together its precursors.
A molecule contains two atoms of oxygen six atoms of hydrogen atoms of carbon. What is the formula of the molecule?
The formula of the molecule is C1H6O2, indicating the presence of one carbon atom, six hydrogen atoms, and two oxygen atoms in the molecule.
The formula of the molecule can be determined by listing the number of each type of atom and using their respective symbols.
Number of oxygen atoms = 2
Number of hydrogen atoms = 6
Number of carbon atoms = 1
Since there are two oxygen atoms, we use the subscript "2" for oxygen: O2. Since there are six hydrogen atoms, we use the subscript "6" for hydrogen: H6. Since there is one carbon atom, we don't need to specify a subscript for carbon: C
Using the symbols for each element, we can write the formula of the molecule:
C1H6O2
Therefore, the formula of the molecule comes out to be C1H6O2.
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Scientist at the CDC (Center for Disease Control) in Atlanta, GA are currently developing and testing new treatments and vaccines for the coronavirus. What kind of research are they conducting?
Answer:
Applied research
Explanation:
The process of developing a new vaccine involves the use of known scientific theories to address specific problems. Here, the outcome of several basic research are put into use to arrive at a targeted outcome. This outcome/product can be continuously modified (if it shows early promise) until the desired effect is achieved and if no "promise" is discovered at critical points of this research, work on this theory (for this research) is suspended another theory is pursued.
This process (described above) in which scientists continuously develop new treatments and/or vaccines and continuously subject it to testing until the desired effect is achieved can be referred to as Applied research.
write the formula for the conjugate acid for each substance below. Please include states of matter.
F- (aq)= HF
Cl- (aq) = HCl
NH3 (aq) = NH4+
I have found the conjugate acids but not the states. how can I find the states?
To determine the states of matter for the conjugate acids, we can consider their common forms when dissolved in water.
F- (aq) -> HF (aq)
Cl- (aq) -> HCl (aq)
NH3 (aq) -> NH4+ (aq)
F- (aq) represents the fluoride ion in aqueous solution. Its conjugate acid is HF (aq), which stands for hydrofluoric acid. When dissolved in water, F- acts as a base and can accept a proton to form HF.
Cl- (aq) represents the chloride ion in aqueous solution. Its conjugate acid is HCl (aq), which stands for hydrochloric acid. When dissolved in water, Cl- acts as a base and can accept a proton to form HCl.
NH3 (aq) represents ammonia in aqueous solution. Its conjugate acid is NH4+ (aq), which stands for ammonium ion. Ammonia acts as a base and can accept a proton to form the ammonium ion, NH4+.
The states of matter for the conjugate acids are given as (aq), indicating that they are in aqueous solution when dissolved in water.
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how many moles of electrons are transferred in the electrochemical reaction represented by the balanced equation 3mn(s) 2au3 (aq) → 3mn2 (aq) 2au(s)?
In the electrochemical reaction represented by the balanced equation 3Mn(s) + 2Au₃⁺(aq) → 3Mn₂+(aq) + 2Au(s), a total of 6 moles of electrons are transferred.
The balanced equation provides the stoichiometric coefficients of the reactants and products, which represent the mole ratios in the reaction. In this case, the coefficient of Mn(s) is 3, and the coefficient of Au³⁺(aq) is 2. This means that for every 3 moles of Mn atoms and 2 moles of Au⁺ ions involved in the reaction, 3 moles of Mn²⁺ ions and 2 moles of Au atoms are produced.
Since the balanced equation does not specify the number of electrons involved in the transfer, we need to consider the changes in oxidation states of the elements to determine the number of electrons spectator ions transferred. In this reaction, each Mn atom loses 2 electrons, going from an oxidation state of 0 to +2, while each Au³⁺ ion gains 3 electrons, going from an oxidation state of +3 to 0.
Therefore, for every 3 moles of Mn atoms that lose 2 electrons each and 2 moles of Au³⁺ ions that gain 3 electrons each, a total of 6 moles of electrons are transferred in the reaction.
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Wendy wants to find out if a substance is an acid or a base. What are two ways that Wendy could
investigate to find out what kind of substance it is?
Without tasting a colorless liquid, an acid or a base can be determined using indicators.
The three most common indicators to test for acids and bases are: Litmus. Methyl orange. Phenolphthalein.
How do you know something is an acid?One practical method for determining how acidic something is is to use the pH scale. A solution is acidic if its pH is less than 7. If the pH of the solution is 7, it is neutral; if the pH is greater than 7, it is basic.To identify acids and bases, two types of litmus paper are available: red litmus paper and blue litmus paper. When exposed to acidic conditions, blue litmus paper turns red, while red litmus paper turns blue when exposed to basic or alkaline conditions.
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What is the condensed structure formula of Pentyne (C5H8) ?
Answer:
Molecular Formula C5H8
Explanation:
Convert 5.00 moles of carbon to grams. Be sure to report your answer with the correct significant figures.
1 moles Carbon to grams = 12.0107 grams
2 moles Carbon to grams = 24.0214 grams
3 moles Carbon to grams = 36.0321 grams
4 moles Carbon to grams = 48.0428 grams
5 moles Carbon to grams = 60.0535 grams
6 moles Carbon to grams = 72.0642 grams
7 moles Carbon to grams = 84.0749 grams
8 moles Carbon to grams = 96.0856 grams
9 moles Carbon to grams = 108.0963 grams
10 moles Carbon to grams = 120.107 grams
Mole measure the number of elementary entities of a given substance that are present in a given sample. Therefore, 60g is the mass of 5.00 moles of carbon.
What is mole?The SI unit of amount of substance in chemistry is mole. The mole is used to measure the quantity or amount of substance. We know one mole of any element contains 6.022×10²³ atoms which is also called Avogadro number.
Mathematically, the formula for mole can be given as
mole of carbon =given mass of carbon ÷ molar mass of carbon
number of mole of carbon= 5.00 moles
mass of carbon=?
molar mass of carbon= 12.0107 grams
Substituting the values in above formula we get
5.00 moles = mass of carbon ÷12.0107 grams
On calculations, we get
mass of carbon =60g
Therefore, 60g is the mass of 5.00 moles of carbon.
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What happens to the particles in a longitudinal wave as the amplitude increases?
Answer:
Explanation:
In a longitudinal wave, particles of the medium move back and forth in the same direction as the wave. Wave amplitude of a longitudinal wave is the distance between particles of the medium where it is compressed by the wave. The closer together the particles are, the greater the amplitude of the wave.
Answer: The particles in a longitudinal wave rotate in the same direction as the amplitude increases.
Explanation: A longitudinal wave's amplitude is the distance between particles in the medium compressed by the wave. The greater the amplitude of the wave, the closer the particles are together.
Atoms of the same element with a different number of neutrons.
Answer:
My answer is: IsotopesExplanation:
Question 9 (5 points) For the following reaction, the change in free energy, AGº, is 4.15 kJ/mol at 25°C. Determine the equilibrium constant
N204 + 2NO2 a) 1.91 b) 0.19 c) 6.74 d) -1.91
The equilibrium constant for the reaction is 0.19, which corresponds to option (b).
Determine the equilibrium constant N204 + 2NO2 a) 1.91 b) 0.19 c) 6.74 d) -1.91?The equilibrium constant (K) can be calculated using the following formula:
AGº = -RT ln(K)
where R is the gas constant (8.314 J/mol·K), T is the temperature in Kelvin, and ln is the natural logarithm.
First, we need to convert the temperature from Celsius to Kelvin:
T = 25°C + 273.15 = 298.15 K
Now, we can substitute the values into the formula:
4.15 kJ/mol = -(8.314 J/mol·K)(298.15 K) ln(K)
Simplifying:
ln(K) = -4.15 × 10^3 J/mol ÷ (8.314 J/mol·K × 298.15 K) = -1.661
Taking the exponential of both sides:
K = e^(-1.661) = 0.19
Therefore, the equilibrium constant for the reaction is 0.19, which corresponds to option (b).
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Okay, I need help with this question. I was really confused because the video didn't really tell me anything, so if someone can help me out it would really help
8. Help Mosa solve the mystery. What is different about the “suspicious” sugar? What is the reason behind Chef Crystal’s terrible creme brulee?
The suspicious sugar clumped together and did not dissolve easily and also had an unusual smell.
The reason behind Chef Crystal's terrible creme brulee may be due to the contaminated sugar used in the recipe.
What are the properties of the sugar?Simple sugars are crystal-like, colorless solids. They taste pleasant, and mix easily in water, but don't crystallize effectively from solutions.
The functions of added sugar in food as a sweetener, preservative, texture modifier, fermentation substrate, flavoring and coloring agent, and bulking agent are the most significant.
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which statement about the rate of decomposition is generally true? a ambient temperature does not affect the rate of decomposition. b decomposition will occur faster if the body is submerged in water than if it is on land. c the body of an overweight person will decompose faster than the body of a person who was not overweight. d a buried body decomposes more slowly than a body that is not buried.
The statement that is generally true about the rate of decomposition is d) a buried body decomposes more slowly than a body that is not buried.
When a body is buried, it is removed from the natural environment that promotes decomposition, such as exposure to insects and air. Burial slows down the decomposition process and can preserve the body for a longer period of time. Factors such as ambient temperature, water submersion, and weight of the person do affect the rate of decomposition but are not generally true for all cases.
Therefore the answer is (d) a buried body decomposes more slowly than a body that is not buried.
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An organic compound containing 40% carbon, 6.67% hydrogen and rest of oxygen, has the molecular mass 180g.mol-1. Find out the EF as well as MF of the compound.
Answer:
The EF of the compound is CH2O and the MF is C6H12O6.
Explanation:
To find the empirical formula (EF) of the compound, we need to determine the simplest whole number ratio of the atoms in the compound. We can assume we have 100 g of the compound, which means we have:
40 g of carbon
6.67 g of hydrogen
53.33 g of oxygen (since the rest of the compound is oxygen)
Next, we can convert the masses to moles:
Moles of carbon = 40 g / 12.01 g/mol = 3.33 mol
Moles of hydrogen = 6.67 g / 1.01 g/mol = 6.61 mol
Moles of oxygen = 53.33 g / 16.00 g/mol = 3.33 mol
We then divide each of the mole values by the smallest number of moles, which is 3.33, to get the simplest whole number ratio:
Carbon: 3.33 / 3.33 = 1
Hydrogen: 6.61 / 3.33 = 1.98 (rounded to 2)
Oxygen: 3.33 / 3.33 = 1
So the EF of the compound is CH2O.
To find the molecular formula (MF), we need to know the molecular mass of the EF. The empirical formula mass (EFM) of CH2O is:
EFM = (1 x 12.01 g/mol) + (2 x 1.01 g/mol) + (1 x 16.00 g/mol) = 30.03 g/mol
We can then calculate the molecular formula mass (MFM) by dividing the given molecular mass (180 g/mol) by the EFM:
MFM = 180 g/mol / 30.03 g/mol = 6
This means the MF is 6 times the EF, or C6H12O6. Therefore
A ball has a mass of 0.5g and a volume of 10mL. Calculate the density
Answer:
0.05g/ml
Explanation:
density is equal to mass over volume check pic for more info
this is a tiny unit of an element that retains the properties of the element.
The tiny unit of an element that retains the properties of the element is called an atom.
Atoms are the basic building blocks of matter and are composed of a nucleus, which contains positively charged protons and neutral neutrons, surrounded by negatively charged electrons that orbit the nucleus. The unique arrangement of protons, neutrons, and electrons in an atom determines its chemical and physical properties, such as its atomic number, mass, and reactivity.Atoms are incredibly small and are typically measured in units of picometers or angstroms.
Each element is defined by the number of protons in its atomic nucleus, which is known as its atomic number. For example, carbon atoms have six protons in their nucleus, while oxygen atoms have eight protons. The number of neutrons in an atom's nucleus can vary, resulting in isotopes of the same element with different atomic masses.
Atoms can combine with other atoms to form molecules and compounds through chemical bonds, including covalent bonds, ionic bonds, and metallic bonds.
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Name a property of liquids that they do not share with solids.
Answer:
a solid has definite volume and shape, a liquid has definite volume but no definite shape, and a gas has neither a definite volume nor shape the change from solid to liquid usually does not significantly change the volume of a substance
The diagram on the left shows a ball on the end of a string being whirled in a circle. The diagram on the right shows the whirling ball as
viewed from above.
(View from above)
After several whirls, the string is released when the ball is at Q. Which of these diagrams shows the direction in which the ball will fly
the instant the string is released?
Answer:B, because this picture move to B
Which of the processes represented by the following chemical equations are endothermic?
Choose one or more:
a. heat Cao(s) +3C(s) --> CaC2 (s)+co(g)
b. CH4(g)+2O2 --> CO2(g) +2H2O(g)+heat
c. CH3OH(g) + 3/2 O2(g) --> CO2(g) + 2H2O(g) AH = -676 kj/mol
d. 2H2O(g) --> 2H2 (g)+O2(g) AH = +483.6 kj/mol
e. I2 (s) --> I2 (g)
The processes represented by chemical equations that are endothermic are:
a. heat Cao(s) +3C(s) --> CaC2 (s)+co(g)b. CH4(g)+2O2 --> CO2(g) +2H2O(g)+heatc. CH3OH(g) + 3/2 O2(g) --> CO2(g) + 2H2O(g) AH = -676 kj/molOption A is an endothermic process because it requires heat input for the reaction to occur. Option B and C are also endothermic processes because they require heat input for the reaction to occur.
Option D is an exothermic process because it releases energy as the water molecules are converted into hydrogen and oxygen molecules. Meanwhile Option E is not a chemical reaction but a physical change known as sublimation. It does not involve a change in enthalpy.
The enthalpy change of a chemical reaction determines whether it is endothermic or exothermic. An endothermic reaction requires the input of energy while an exothermic reaction releases energy.
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How many moles of magnesium (Mg ) metal would be produced if 12 moles of potassium (K ) reacted?
As per the given reaction one mole of magnesium hydroxide reacts with 2 moles of potassium metal to give one mole of Mg. Therefore, 12 moles of potassium reacts to give 6 moles of Mg metal.
What is displacement reaction ?In a displacement reaction, one element or group is displaced from the reactant by the other reactant. The given reaction is an example of single displacement reaction.
As per the balanced chemical equation of the reaction, 1 mole of magnesium hydroxide reacts with 2 moles potassium metal to form one mole of Mg metal and 2 moles of potassium hydroxide.
Here, 12 moles of potassium is taken. Then, the number of moles of Mg metal formed is just half the number of moles of K. That is 6 moles of magnesium metal.
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The reaction related to your question is given below:
Mg(OH)₂ + 2K ⇒2KOH + Mg
Can I get help with question 13 ? I don’t understand how to solve it
Answer
10.6 liters
Explanation
What is given:
Density of the gasoline = 0.680 g/mL
Mass of the gasoline = 7.20 kg
What to find:
To find how large of a container, (volume) in liters needed to hold the gasoline.
Step-by-step solution:
Step 1: Convert the mass of gasoline from kg to g.
Conversion factor: 1 kg = 1000 g
So 7.20 kg = (7.20 kg/1 kg) x 1000 g = 7200 g
Step 2: Determine the volume in mL using the density equation.
\(\begin{gathered} Density=\frac{Mass}{Volume} \\ \\ 0.680\text{ }g\text{/}mL=\frac{7200\text{ }g}{Volume\text{ }in\text{ }mL} \\ \\ Volume\text{ }in\text{ }mL=\frac{7200\text{ }g}{0.680\text{ }g\text{/}mL}=10588.24\text{ }mL \end{gathered}\)Step 3: Convert the volume in step 2 from mL to liters.
Conversion factor: 1000 mL = 1 L
So, 10588.24 mL = (10588.24 mL/1000 mL) x 1 L = 10.58824 liters
How large of a container, (volume) in liters needed to hold 7.20 kg of gasoline is approximately 10.6 liters
Nitrogen gas, N2, reacts with hydrogen gas, H2 to form ammonia, NH3.
3 H2(g)+ N2(g) → 2 NH3(g)
If 5.40 L of ammonia gas is collected at 25.60 °C and 761.0 mmHg, how many grams of nitrogen gas are consumed? The molar mass of nitrogen gas is 28.0134 g/mol.
Ammonia has a molar mass of 17 g/mol. Ammonia weighs 68 grammes, or 17g/mol. 68g=4moles From 241 = 2 moles of nitrogen and 243 = 6 moles of hydrogen, 4 moles of ammonia will be produced. Nitrogen and hydrogen have molar weights of 28 g/mol and 2 g/mol, respectively. 56 grammes are equivalent to 2 moles of nitrogen, or 228. 6 moles of hydrogen are equivalent to 12 grammes (62).
From 50.0 grammes of the nitrogen gas 3h2 N2 --> 2nh3, how many grammes of ammonia are produced?
We need to determine how many moles of nitrogen there are in this 50 g of nitrogen gas. We would generate 1.792=3.58 moles of ammonia from this point. 3.58 mol; 17.031 gmol; 61 g of NH3
42 grammes of nitrogen may be converted into how many grammes of ammonia?
b The mass of N and H in the ammonia molecule, NH3, is equal to 14 + 3 1 = 17. The amount of H needed to react with 14 g of N is 3 g. Hence, the mass of H needed to react with 42 g of N is equal to 3/14 42 = 9 g.
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calculate the molality of a 15.0% by mass solution of mgcl2 in h2o. the density of this solution is 1.127 g/ml.
The molality of a 15.0% by mass solution of mgcl2 in h2o is 1.86 m.
Define molality.
The molality of a solution is defined as the number of moles of solute particles present in one kilogram of a solvent. In general, the molality expresses the concentration of a solution. In this case, water acts both as a solute and a solvent.
Given:
Mass solution of MgCl₂ in H₂O= 15%
Density= 1.127g/mL
To find:
Molality=?
Let's solve this question step by step:
Step 1: Calculate the mass of solute and solvent in 100 grams of solution
As it is given that 15.0% by mass solution of MgCl₂ (solute) in H₂O (water).
In 100 g of solution, there are 15.0 g of solute and 100.0 g - 15.0 g = 85.0 g of solvent.
Step 2: Calculate the moles corresponding to 15.0 g of MgCl₂
The molar mass of MgCl₂ is 95.21 g/mol.
Number of moles is given mass divided by the molar mass.
Number of moles= 15g/95.21 g/mol
=0.158 mol
Step 3: Convert the mass of water to kilograms.
As we know, 1 kg = 1,000 g.
=85/1000= 0.085 kg
Step 4: Calculate the molality of the solution.
Molality is a measure of the number of moles of solute in a solution corresponding to 1 kg or 1000 g of solvent.
Molality= 0.158 mol/0.085 kg
= 1.86 m.
Therefore, the molality of a 15.0% by mass solution of mgcl2 in h2o is 1.86 m.
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When preparing a solution in a cuvette, make sure to handle the cuvette by the_____________ and avoid touching the __________ then, __________- the cuvette before placing it in the spectrophotometer.
When preparing a solution in a cuvette, make sure to handle the cuvette by the textured sides,and avoid touching the smooth sides, then, wipe down the cuvette before placing it in the spectrophotometer.
A cuvette is a little tube-shaped container with round or square cross section and straight sides. It is formed of a clear, transparent substance like plastic, glass, or fused quartz and is sealed at one end.
A spectrophotometer is a device that counts the number of photons (light's energy) absorbed after they have passed through a sample solution. By measuring the intensity of light detected, the spectrophotometer may also estimate the quantities of a known chemical compound.
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When preparing a solution in a cuvette, make sure to handle the cuvette by the textured sides,and avoid touching the smooth sides, then, wipe down the cuvette before placing it in the spectrophotometer.
A cuvette is a little tube-shaped container with straight edges and a round or square cross section. It is made of a clear, translucent material with a sealed end, such as plastic, glass, or fused quartz.
A spectrophotometer measures the quantity of photons—the energy of light—that are absorbed after passing through a sample solution. The spectrophotometer can also estimate the amounts of a known chemical substance by measuring the intensity of light that is observed.
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A gas has a volume of 900.0 mL at 35.0°C and 400.0 atm. What would the volume of the gas be at 258 °C and 700.0 atm of pressure?
Answer:
887 ML
Explanation:
yup
What general trend does electronegativity follow on the periodic table?
A. It increases from top to bottom.
B. It decreases from top to bottom.
C. It decreases with increasing atomic number.
D. It increases with increasing atomic number.
Answer:
B.) It will decrease from top to bottom
Explanation:
just got the answer right and looked on khan academy XD
The electronegativity of elements in the periodic table decreases from top to bottom. Details about periodic table can be found below.
What is periodic table?Periodic table refers to a tabular chart of the chemical elements according to their atomic numbers so that elements with similar properties are in the same group or column.
Electronegativity of elements is the tendency or a measure of the ability of an atom or molecule to attract electrons and thus form bonds.
In accordance to the arrangement of elements on the periodic table, the electronegativity of elements in the periodic table decreases from top to bottom.
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Which has more kinds of specialized cells, a tissue or an organ?
Answer:
An organ would have more kinds of specialized cells because it is made up of different tissues.
What is the empirical formula for a compound with a molecular formula of C12H18N606?
Type the subscripts in the blanks
The empirical formula for a compound with a molecular formula of C₆H₉N₃O₃.
What is empirical formula?Empirical formula of a compound is defined as the simplest whole number ratio of atoms which are present in a compound.It does not make any mention of the arrangement of atoms or the number of atoms. The empirical formula gives information about the ratio of number of atoms which are present in a compound.
Molecular formula is determined from the empirical formula by dividing the molar mass of a compound by the empirical formula mass. The resultant which should be a whole number or very close to the whole number , then the subscripts are multiplied by the whole number to get the molecular formula.The mentioned empirical formula is obtained by dividing molecular formula by 2.The empirical formula is obtained as , molecular formula/2=C₁₂H₁₈N₆O₆/2=C₆H₉N₃O₃
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What happens to energy when a bat hits a ball?
the ball starts moving
the energy changes form
kinetic energy moves from the bat to the ball
the total energy increases when the ball moves
HELP
Answer:
the ball starts moving
the energy changes
What are user-defined details about a file that describe its content and origin called?.
Document properties are user-defined details about a file that describe its content and origin.
They are also called metadata because they are data that describe other data for structure and organization. These details commonly refer to the title, the author or editor's name, the subject, and those keywords that give identity to the document's content.
There are four types of Document Properties, and with the help of Microsoft, we can list them:
- Standard properties: refer to details such as author, title, and subject
- Automatically updated properties: these are defined automatically and refer to file system properties, including the file size and dates of creation or modification. Also, involve statistics properties such as the number of characters or words in a file.
- Custom properties: are additional details that the user can define, like the numeric value o text time.
- Document library properties: indicate the properties of the document in a public website or folder
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According to the
graph, what happens
to the concentration
of A over time?
Concentration (M)
Reaction: 2A A₂
Time (sec)
A. It decreases and then levels out.
B. It decreases consistently.
C. It increases and then levels out.
D. It increases consistently.
The concentration of A decreases and then levels out. Option A
How does concentration of the reactant change?
In many chemical reactions, a reactant is consumed as the reaction progresses, leading to a decrease in its concentration over time. The reactant molecules are transformed into products, and as the reaction proceeds, the concentration of the reactant gradually diminishes.
At equilibrium, the concentrations of both reactants and products remain relatively constant over time, although they can coexist.
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